• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:

    公开号:SU1812955A3
    申请号:SU894613970
    申请日:1989-05-15
    公开日:1993-04-30
    发明作者:Albert Perfetti Tomas；Vilbur Vorrell Geri
    申请人:R Dzh Rejnolds；
    IPC主号:
    专利说明:

    The invention relates to smoking articles.
    The invention relates to a smoking article including a fuel cell, physically separated aerosol generating means, a separate mouthpiece and improved means for releasing menthol and other volatile flavoring agents together with aerosol without any significant migration of the flavoring agent into the fuel cell or other components of the smoking article.
    Improved fragrance release means include a carbon-filled sheeting located in a non-frizzy portion of the article, such as any portion of the article that is longitudinally behind the fuel cell or at · </-A;..-... ----- a single piece and an improved means for supplying a smoker with one or more flavoring agents, which is provided with a carbon-filled sheet material located in a non-combustible part of the smoking article, carrying or otherwise containing one or more flavoring agents. More particularly, the present invention relates to a globular foamed tobacco sheet for use as at least part of the mouthpiece of such articles, carrying flavoring agents, in particular vivoCo Volatile flavoring agents like menthol. 5 p.p. f-ly, 3 dwg
    some distance from this fuel cell. However, according to the preferred embodiment, it should be made in the form of a Cylindrical segment Or a plug located between the aerosol- generating means and the mu n D pc U k0M of the smoking article.
    The improved flavor release agents of the present invention help to reduce the migration of flavoring agents, in particular menthol and other volatile flavorings, to other components of the smoking article or equipment that used in the manufacture of such products. ''
    Flavoring agents are easily and evenly released from the carbon-filled sheet material during smoking, when the aerosol and hot gases from the aerosol SU 1812955 AZ, sol-generating means pass the incense through this sheet material. It is believed that a temperature that is slightly above normal aerosol temperature, ie, about 150 ° C or so, 5 immediately behind the aerosol generating means will release uniform amounts of the flavoring agent over the life of the smoking article.
    The carbon-filled sheet material Yu of the invention also acts as a heat sink, which helps to reduce the temperature of the aerosol that is perceived by the smoker, and also helps prevent unwanted decomposition or melting of the filter material.
    Smoking articles incorporating the improved fragrance release agents of the invention are capable of releasing at least 0.6 mg aerosol as determined by measuring the total wet particle count (TWC) in the first 3 puffs when p process kure-. The treatments are carried out in an FTC smoking environment, which includes .35 mm puffs of two seconds duration, separated by 58 second breaks of smoldering.
    FIG. 2.1 - implementation of a method for manufacturing a cylindrical segment from 3Q carbon-filled sheet material in the form of a filter plug; on fip 2A - a double cone system, which is used to fold or fold the material to give it the shape of a filter plug; in fig. 2.2 is a longitudinal sectional view of a cigarette using the improved flavor release means in accordance with the '40 invention; in fig. 2a is a burning end view of a preferred embodiment of a duct system in a fuel cell; in fig. 2.3 is a study of migration in cigarettes using 45 and no carbon-filled sheeting of the invention.
    The present invention provides improved fragrance release means for use in smoking articles. Such fragrance release means are particularly suited to smoking articles equipped with a small hot fuel cell, physically separated aerosol generating means and a separate mouthpiece.
    Typically, improved flavor release agents include carbon-filled sheeting, typically made by adding carbon (activated, unactivated, or mixtures thereof) to conventional furnish, such as pulped wood or flax and / or pulped tobacco stems or trunks. The material is then formed into sheet material in accordance with conventional papermaking techniques.
    The carbon content of the sheeting can vary widely, depending on a number of factors, including the type and amount of coal and / or flavoring agent used, the location of the carbon-filled sheeting in the smoking article, and the shape or configuration of the sheeting. Typically, the coal content is in the range from about 5 to about 75% by weight of the sheet material. Despite the possibility of using larger amounts of coal, the production of sheet material with more than about 75 wt.% Coal is associated with technological limitations in the production of paper, as well as with limitations in the characteristics of the manufactured paper, for example, tensile strength, increased dust formation and related problems.
    Although either activated carbon or non-activated carbon can be used as the carbon component of the sheet material, activated carbon is more preferable.
    Charcoal-filled sheeting can be made using conventional furnish. In a preferred embodiment, it can be made from a mixture of wood fiber with pulp made from tobacco stems or trunks. The carbon component of the sheet material is usually added to the slurry of the pulped materials and from the mixture thereof, the sheet material is formed using conventional papermaking equipment.
    Flavoring agents can be added to the charcoal-filled sheet material in any order and by any means, such as spraying, dipping, painting, vapor deposition, and the like. According to the proposed embodiment, the flavoring agent is applied to the sheet material according to the vapor deposition technique.
    ... For the practical implementation of the invention, any number of flavoring agents can be used, in particular menthol, vanillin, artificial coffee, tobacco extracts, nicotine, nicotine salts, caffeine, decoctions, cocoa butter and other products that improve the aerosol aroma formed when smoking the product ...
    The amount of a flavoring agent that is introduced into the sheet material by impregnation or otherwise can vary over a wide range depending on the type of flavoring agent, its route of introduction, the carbon content in the sheet material, the activity of coal, the arrangement of the sheet material in the smoking article, the procedure by which subjecting the sheet material when it is introduced into the smoking article, that is, curling, folding, collecting or some other action, and the like.
    As noted above, in some preferred embodiments, the carbon-filled sheeting is positioned between the aerosol generating means and the mouthpiece filter, more preferably in the form of a 'cylindrical filter plug. A cylindrical or other suitable shape of a conventional filter plug can be imparted to the sheeting by practicing conventional cigarette filter technology, in particular a conventional filter making machine used to make cellulose acetate strands.
    FIG. 1 is an illustration of one embodiment of means for forming a filter plug from a carbon-filled sheet material. A roll 1 of flavored carbon-filled sheet material 2 is unwound and fed into a preforming cone 3 in which the sheet material is collected or folded into a cylindrical shape suitable for passage into a cylinder plug machine.
    For the manufacture of multi-segment or multilayer aroma release means, two or more charcoal-filled sheet materials of different properties, for example, with different carbon contents, aromatizing agents, and the like, can be processed separately or simultaneously. This shaped cylinder 4 is wrapped in wrapping paper 5 and the whole combination is cut with a cutter 6 into pieces of the desired length 7. A continuous bead of glue is applied to the rim of the wrapping paper with an applicator prior to insertion into the headset. As these components pass through the headset, the formed cylinder 4 is further compressed into a rod with a cylindrical cross-section, while at the same time it is wrapped in a wrapping paper casing. Once the adhesive strip has entered into contact with the overlapping section of the wrapped rod, it is sealed with a sealing bar. This endless cylindrical rod is then cut into pieces with a cutter.
    Alternatively, instead of a single cone, a double cone system is provided (see Fig. 3A). This system has a cone in a cone as a preforming unit. The charcoal-filled sheeting is fed into the annular space between the cones & a virtually tension-free state, whereby at the inlet, the lire material wraps around a radical portion of the inner cone. These cones are able to move relative to each other to achieve the desired uniformity and strength of the cylindrical segment.
    While it is not essential to the production of suitable cylindrical segments of the carbon-filled flavored sheet material, the sheet material itself allows it to be further treated with flavoring agents prior to forming a cylindrical segment therefrom. Two such treatments can be performed with. a pair of grooved rollers 8 used for folding and a liquid applicator 9 that is used for surface treatment of the sheet material, for example menthol, glycerin or other flavoring agents or humectants.
    In preferred embodiments, in which the carbon-filled sheeting is placed between the aerosol generating means and a mouthpiece or filter in the form of a cylindrical segment or plug, the length of the carbon-filled flavored sheeting segment typically varies depending on the type and amount of flavoring agent used. In cigarettes using the mouthpiece described in Example 1, the length of the carbon-filled sheeting segment is typically in the range of about 5 to 30 mm.
    Considering the performance and / or aesthetic point of view, the strength of the aromatized segment of carbon-filled sheet material used in accordance with the invention can be varied over a wide range, but should not affect the release of aerosols. However, it is desirable
    Ί have a segment that feels and has the strength of a cigarette, enclosing a conventional cellulose acetate filter.
    In a preferred embodiment, the total pressure drop due to smoking articles using the improved flavor release agents in accordance with the invention should be the same or less than the pressure drop in other cigarettes. The pressure drop in the carbon-filled sheet material and the filter material in the mouth piece itself changes depending on the drop at the front of the smoking article,
    In smoking articles, in particular those described in Example 1 cited, the pressure drop is typically less than the pressure drop across conventional filter plugs, typically in the range of about 0.1 to 6.0 cm H2O. The pressure drop across the filter is the pressure drop in centimeters of water as an air flow of 1050 cc / min passes through the filter sample. These pressure drops can be converted to the unit filter plug length by dividing by the actual filter length.
    FIG. 2 shows an image of a cigarette equipped with a small carbonaceous fuel cell 10 with a plurality of channels 11 passing through it, approximately 30 channels arranged as shown in Fig. 2A.
    On the outside 12, the fuel cell 10 is surrounded by an elastic jacket made of heat-insulating fibers 13, in particular glass fibers.
    A portion of the mouthpiece of the fuel cell 10 is enclosed by a metal capsule 14 that encloses a physically separated aerosol generating means containing a substrate material 15 carrying one or more aerosol generating materials.
    The capsule is surrounded by a tobacco filler sleeve 16. The mouthpiece part of the capsule provides for the presence of two slit-like channels 17 passing in the central part of the corrugated tube.
    At the mouth end of the tobacco sleeve, a mouth portion 18 is provided, including a cylindrical segment of the flavored carbon-filled sheet material 19 and a segment of nonwoven thermoplastic fibers 20 through which the aerosol passes to the consumer. The entire product or parts of it are wrapped on the outside with one or more layers 21-27 of cigarette luncheon paper.
    The carbon-filled sheet material could be shredded and included as all or part of the tobacco tube, or it could be used as one or more non-combustible wrappers used to combine the various components of the smoking article.
    When the above cigarette is ignited, the fuel cell burns, generating heat, which is used to sublimate the tobacco flavoring agent and any additional aerosol forming agent or substances in the aerosol generating agent and tobacco sleeve. Since the preferred fuel cell is relatively short, hot, the burning cone of fire is always close to the aerosol generating means, which maximizes heat transfer to the aerosol generating means and the tobacco sleeve and the resulting formation of aerosol and tobacco flavoring agents, especially when a heat transfer element is used in the preferred embodiment. ... The hot gases, aerosol and flavoring agents from the spray generating agent and tobacco tube heat the flavored carbon-filled sheet material, which releases the flavoring agent contained therein.
    Due to its small size and combustible characteristics, the fuel cell begins to burn practically along its entire length after just a few puffs. Thus, this part of the fuel cell, which is adjacent to the aerosol generator, quickly becomes hot, which significantly increases the heat transfer to the aerosol generator and tobacco sleeve, especially during the first and middle puffs. Because the preferred fuel cell turns out to be so short, in all cases there is no long section of non-combustible fuel that acts as a heat sink. This in turn raises the temperature that acts on the flavored carbon-filled sheet material, which enhances the release of the flavoring agent from the carbon component of the sheet material. However, since the aerosol and tobacco flavor products as well as the flavoring agent of the carbon-filled sheet material are physically separated from the fuel cell, they are exposed to significantly lower temperatures than those. which are created by a fuel cell, due to which the possibility of thermal degradation of aromatizing and aerosol-forming products is minimized.
    The proximity of the hot cone to the aerosol generator and tobacco sleeve after several puffs in combination with an insulating element results in high heat transfer both during puffs and during relatively long smoldering periods between puffs.
    Typically, the diameter of the fuel cell contemplated for use in the preferred embodiments does not exceed the diameter of a cigarette (i.e., less than or equal to 8 mm), and its pre-smoke length is typically less than about 30 mm. In the proposed embodiment, the length of the fuel cell should be about 15 mm or less, more preferably about 10 mm or less. The preferred diameter of the fuel cell is about 2 to 8 mm, more preferably about 4 to 6 mm. The density of the fuel cell used in such cases can typically range from about 0.7 to 1.5 g / cm 3 .
    The carbon content of the fuel cells is at least 60 to 70% by weight. A high content of coal in fuel cells is preferable because they generate a minimum amount of pyrolysis products and incomplete combustion, little or no appreciable amount of sidestream smoke, a minimum amount of ash combined with a high heat capacity.
    The aerosol generating means that are used in the practice of the invention are physically separated from the fuel cell. This separation helps to reduce or eliminate thermal decomposition of the aerosol product and the formation of a sidestream smoke stream. Not being part of the fuel cell, the aerosol generating means, preferably its ends, are connected or otherwise communicated by the fuel cell in such a way that the fuel cell and the aerosol generating means are interconnected in a heat exchange and heat conducting relationship.
    The aerosol-generating means according to the preferred embodiment should be no more than 15 mm from the burning end of the fuel cell. The length of the aerosol generating means can vary from about 2 mm to 60 mm. The diameter of the aerosol generating means can range from about 2 to 8 mm, more preferably from about 3 to 6 mm.
    In a preferred embodiment, the aerosol-generating means should include one or more heat-resistant materials that carry one or more aerosol-generating agents.
    The class of useful thermally stable materials includes adsorption coals, in particular porous coals, graphite, activated and reactivated coals, etc. Other suitable materials include inorganic solids such as bentonite and mixtures thereof.
    A particularly useful silica substrate is silica with a high specific surface area.
    The aerosol-forming product or products used in the articles of the invention must be capable of accommodating amounts that are typically between about 20 and 140 mg,
    The aerosol generating agent may also include one or more volatile flavoring agents such as menthol, vanillin, artificial coffee, tobacco extracts, nicotine, caffeine, decoctions, and other agents that improve the flavor of the aerosol.
    One particularly preferred aerosolizing agent comprises the above-mentioned silica substrate containing spray-dried tobacco extract, levulinic acid or glucose pentaacetate, and an aerosolizing agent such as glycerin.
    The tobacco filling can be placed after the fuel cell. In these cases, hot vapors rush through the tobacco, extracting and evaporating volatiles from it without burning or significant pyrolysis. Thus, the consumer receives an aerosol that contains the taste and aroma components of natural tobacco without intensive combustion of products that are formed in a conventional cigarette.
    The thermally conductive material used in preferred embodiments in the form of a container for the aerosol generating agent is usually a metal foil, in particular an aluminum foil, the thickness of which ranges from less than about. from about 0.01 mm to about 0.1 mm or more.
    The disclosed diaphragm element engages or partially encloses the rear of the fuel cell and may form a 'container or sleeve that encloses the aerosol-forming substrate.
    The insulating elements used in preferred smoking articles of the present embodiment should be molded within the jacket from one or more layers of insulating material, and the thickness of the jacket should be approximately 0.5 mm. Preferably, the jacket should extend over more than half, if not the entire length, of the fuel cell. In a more preferred embodiment, it should also cover substantially the entire periphery of the fuel cell and the sleeve for the aerosol generating agent. ...
    The current preferred insulating materials, especially for a fuel cell, are ceramic fibers, in particular glass fibers. To maximize the release of aerosol that might otherwise be radially diluted. By infiltrating air through the product, non-porous paper can be used from the aerosol-generating agent to the mouthpiece.
    For various functional effects, paper such as is known in the cigarette and / or paper art and a mixture of such paper can be used.
    The filter should be provided with a series of openings approximately 23 mm from the mouthpiece of the smoking article that provide approximately 22% air dilution.
    The aerosol emitted by the smoking articles of the invention is chemically simple, consisting mainly of air, carbon oxides, an aerosolizing agent including various desired aroma products or other volatile materials, water and traces of other materials. ...
    In the embodiment of the invention, there is no ash generated during consumption. As the coal fuel cell burns, it is almost completely converted to carbon oxides with the formation of a relatively small amount of ash, so there is no need to shake off the ash during consumption of the smoking article.
    EXAMPLE 1 A cigarette of the type illustrated in FIG. 2.3, made as follows.
    Fuel source fabrication.
    A fuel cell (10 mm long, 4.5 mm outer diameter, apparent density (bulk density) of which was approximately 0.86 g / cm 3 , was made from coal (90 wt.%). NKMC as a binder (10 wt.%) and potassium carbonate (1 wt%).
    The charcoal was prepared by carbonizing Grand Prairie Canadian kraft hardwood paper of a talc-free grade in a nitrogen stream with a gradual temperature rise at a rate of approximately 10 ° C per hour to a final carbonization temperature of 750 ° C.
    After cooling in a nitrogen stream to below about 35 ° C., the coal was ground to a particle size of 200 US mesh. Next, the powdered coal was heated to a temperature of approximately. 850 ° C in order to remove volatiles from it.
    After recooling under nitrogen flow to a temperature below about 35 ° C, the coal was crushed to a fine powder, i. powder with an average particle size of about 0.1 to 50 microns.
    This fine powder was mixed with Hercules 7HF (NKMC) as a binder (9 hours, coal for 1 hour, binding agent), 1 wt.% Potassium carbonate, and sufficient water to prepare a thick, dough-like paste.
    Fuel cells were extruded using this paste into rods, each of which was provided with seven central β-holes approximately 0.53 mm in diameter and six peripheral holes approximately 0.25 mm in diameter. The thickness of the baffle or the distance between the center holes was about 0.20 mm, and the average thickness of the outer baffle (the distance between the peripheral holes and the periphery) was about 0.48 mm.
    Then, these fuel cells were fired in a nitrogen flow at 900 ° C for 3 hours after molding. ...
    Spray-dried ex-tract.
    The pipefly tobacco mixture was pulverized with an average particle size and subjected to a water extraction treatment in a stainless steel tank at a concentration of about 1 to 1.5 feet tobacco per gallon of water [0.453 to 0.680 kg / 3.785 L]. The extraction was carried out at room temperature with mechanical stirring for about 1 to 3 hours. The mixture was then centrifuged to remove suspended solids from it, and the aqueous extract was spray dried by continuously pumping the aqueous solution into an appropriate spray dryer, Anhydro size No. 1, at an inlet temperature of approximately 215-230 ° C and collecting dried powder material at the outlet of the dryer. The outlet temperature ranges from approximately 82-90 ° C.
    Sintered alumina preparation.
    A high specific surface area alumina (specific surface area of about 280 m 2 / g), -14 to 20 US mesh, was calcined at about 1400 to 1550 ° C for about 1 hour, washed with water and dried. After that, the calcined alumina was combined in a two-stage process with the components, preparing the composition of the following composition,%:
    Alumina 68.11
    Glycerin 19.50
    Spray-dried extract 8.19
    HFCS (invertose) 3.60
    Cocoa extract 0.60
    In a first step, the spray dried tobacco extract was mixed with sufficient water to prepare the slurry. This slurry was then applied to the alumina carrier by mixing with it until it was uniformly absorbed by the alumina. The treated alumina was then dried to a residual moisture content of approximately 1 wt%. In a second step, this treated alumina was mixed with a combination of the other listed components, while mixing continued until the liquid was almost completely absorbed by the alumina carrier.
    Assembly.
    The sleeve that was used to make the cigarette was made of deep drawn aluminum. The average wall thickness of this sleeve was approximately 0.1 mm, the length was approximately 30 mm, and the outer! diameter about 4.5 mm. The rear part of this sleeve was sealed, leaving two slit-like holes necessary for the aerosol forming agent to enter the consumer. Approximately 330 mg of aerosol-producing carrier was loaded onto this sleeve. A fuel cell was inserted into the open end of the filled sleeve to a depth of approximately 3 mm.
    Insulation jacket.
    The fuel cell-liner combination was wrapped from the outside on the fuel cell side over its length by 10 mm with a jacket made of Owens-Cornlg Cblass S-158 fiberglass, containing 3 wt.% Of the effective coupling agent, to a diameter of about 7.5 mm. 3 The fiberglass shirt was then wrapped in a cushioning material, Kimberly-Clark experimental paper, marketed as P780-63-5.
    Tobacco tourniquet.
    A 28 mm long, 7.5 mm diameter tobacco rod with a Camburly-Clarke outer wrapper P1487-125 was modified by inserting a pin 10 to make a longitudinal hole with a diameter of approximately 4.5 mm.
    Assembly.
    The jacketed fuel cell-liner combination was inserted into the channel in the tobacco rod 15 until the fiberglass jacketed tobacco was tightly coupled. The fiberglass and tobacco sections were interconnected with a wrapping material, which covered both the combination of a fuel cell (insulating jacket) inner liner and a wrapped tobacco rod. The aligned mouthpiece sections were connected to a jacketed fuel cell aligned to the sleeve section using a 30637-801-12001 Ekusta tipping paper outer wrap.
    Thus produced, the menthol-treated aerosol is released without any undesirable side-taste due to the burning or thermal decomposition of the menthol or aerosol-forming material. Sensory 35 evaluations of such products with commercially available menthol cigarettes, which are characterized by the formation of small amounts of tar, showed identical results on menthol perception and release.
    权利要求:
    Claims (6)
    [1]
    Φ o rm ula and acquisition
    1. A smoking article comprising a fuel cell at the end of the combustion of a smoking article and a physically separated 45 aerosol generating means, including at least one aerosol-forming material arranged to receive heat from the fuel cell, and a separate means for delivering the aerosol generated by the aerosol generating means a smoker, characterized in that, in order to improve the taste when smoking, it includes a cylindrical separating element 55 located in the longitudinal direction between the aerosol generating means and the aerosol delivery means and containing a carbon-filled sheet material carrying at least one flavoring agent.
    [2]
    2. Product by π. 1, characterized in that the aerosol delivery means further comprises a filter plug located at the oral end of the smoking article, and the cylindrical 5 separating element is located immediately in front of it.
    [3]
    3. Product according to PP. 1 and 2, differing from the fact that the content of coal in sheet material is 5-75 May. %.
    [4]
    4. Product according to PP. 1-3, with the fact that menthol is used as a flavoring agent in an amount from 0.001 wt.% To a saturated concentration.
    [5]
    5. Product according to PP. 1-4, because the tobacco content in the leaf material is 65 May. %.
    [6]
    6. Product according to PP. 1-5, characterized in that the length of the cylindrical dividing element is 5-30 mm.
    类似技术:
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    FI81950C|1991-01-10|TOBAKSPRODUKT MED FOERBAETTRADE MEDEL FOER AVGIVANDE AV AROMAEMNEN.
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    RU2764202C1|2018-11-01|2022-01-14|Никовенчерс Трейдинг Лимитед|Composition turned to aerosol|GB759341A|1954-10-08|1956-10-17|Jan Ivo Marek|Improvements in filters and filter material for use in filtering tobacco smoke|
    NL282359A|1961-09-19|
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    US4827950A|1986-07-28|1989-05-09|R. J. Reynolds Tobacco Company|Method for modifying a substrate material for use with smoking articles and product produced thereby|US4989619A|1985-08-26|1991-02-05|R. J. Reynolds Tobacco Company|Smoking article with improved fuel element|
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    US5131416A|1990-12-17|1992-07-21|R. J. Reynolds Tobacco Company|Cigarette|
    US5348027A|1991-02-14|1994-09-20|R. J. Reynolds Tobacco Company|Cigarette with improved substrate|
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    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    US19469688A| true| 1988-05-16|1988-05-16|
    IN303CA1989|IN172374B|1988-05-16|1989-04-19|LV930563A| LV5377A3|1988-05-16|1993-06-11|Smear product|
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